Pedosphere 23(1): 10--19, 2013
ISSN 1002-0160/CN 32-1315/P
©2013 Soil Science Society of China
Published by Elsevier B.V. and Science Press
Use of organic solvents to extract organochlorine pesticides (OCPs) from aged contaminated soils
YE Mao, YANG Xing-Lun, SUN Ming-Ming, BIAN Yong-Rong, WANG Fang, GU Cheng-Gang, WEI Hai-Jiang, SONG Yang, WANG Lei, JIN Xin and JIANG Xin
State Key Laboratory of Soil and Sustainable Agriculture, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008 (China)
ABSTRACT
      Problems associated with organochlorine pesticide (OCP)-contaminated sites in China have received wide attention. To solve such problems, innovative ex-situ methods of site remediation are urgently needed. We investigated the feasibility of the extraction method with different organic solvents, ethanol, 1-propanol, and three fractions of petroleum ether, using a soil collected from Wujiang (WJ), China, a region with long-term contamination of dichlorodiphenyltrichloroethanes (DDTs). We evaluated different influential factors, including organic solvent concentration, washing time, mixing speed, solution-to-soil ratio, and washing temperature, on the removal of DDTs from the WJ soil. A set of relatively better parameters were selected for extraction with 100 mL L-1 petroleum ether (60--90 oC): washing time of 180 min, mixing speed of 100 r min-1, solution-to-soil ratio of 10:1, and washing temperature of 50 oC. These selected parameters were also applied on three other seriously OCP-polluted soils. Results demonstrated their broad-spectrum effectiveness and excellent OCP extraction performance on the contaminated soils with different characteristics.
Key Words:  dichlorodiphenyltrichloroethane, ex-situ soil washing, extraction performance, petroleum ether, site remediation
Citation: Ye, M., Yang, X. L., Sun, M. M., Bian, Y. R., Wang, F., Gu, C. G., Wei, H. J., Song, Y., Wang, L., Jin, X. and Jiang, X. 2013. Use of organic solvents to extract organochlorine pesticides (OCPs) from aged contaminated soils. Pedosphere. 23(1): 10-19.
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