Pedosphere 19(3): 281--291, 2009
ISSN 1002-0160/CN 32-1315/P
©2009 Soil Science Society of China
Published by Elsevier B.V. and Science Press
| Effects of composted and thermally dried sewage sludges on soil and soil humic acid properties |
| J. M. FERNNDEZ1, N. SENESI2, C. PLAZA1, G. BRUNETTI2 and A. POLO1 |
1 Centro de Ciencias Medioambientales, Consejo Superior de Investigaciones Científicas, Serrano 115 dpdo., 28006 Madrid (Spain)
2 Dipartimento di Biología e Chimica Agroforestale e Ambientale, University of Bari, Via Amendola 165/A, 70126 Bari (Italy) |
| ABSTRACT |
| The effect of annual additions of composted sewage sludge (CS) and thermally dried sewage sludge (TS) at 80 t ha-1 on soil chemical properties was investigated for three years in a field experiment under semiarid conditions. Humic acids (HAs) isolated by conventional procedures from CS, TS, and unamended (SO) and sludge amended soils were analysed for elemental (C, H, N, S and O) and acidic functional groups (carboxylic and phenolic) and by ultraviolet-visible, Fourier transform infrared and fluorescence spectroscopies. With respect to CS, TS had similar pH and total P and K contents, larger dry matter, total organic C, total N and C/N ratio and smaller ash content and electrical conductivity. Amendment with both CS and TS induced a number of modifications in soil properties, including an increase of pH, electrical conductivity, total organic C, total N, and available P. The CS-HA had greater O, total acidity, carboxyl, and phenolic OH group contents and smaller C and H contents than TS-HA. The CS-HA and TS-HA had larger N and S contents, smaller C, O and acidic functional group contents, and lower aromatic polycondensation and humification degrees than SO-HA. Amended soil-HAs showed C, H, N and S contents larger than SO-HA, suggesting that sludge HAs were partially incorporated into soil HAs. These effects were more evident with increasing number of sludge applications. |
| Key Words: elemental composition, fluorescence spectroscopy, Fourier transform infrared spectroscopy, functional group composition |
| Citation: FernÁndez, J. M., Senesi, N., Plaza, C., Brunetti, G. and Polo, A. 2009. Effects of composted and thermally dried sewage sludges on soil and soil humic acid properties. Pedosphere. 19(3): 281-291. |
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