Pedosphere 10(1): 21--30, 2000
ISSN 1002-0160/CN 32-1315/P
©2000 Soil Science Society of China
Published by Elsevier B.V. and Science Press
Effect of heavy metal pollution on potassium behavior in Typic Udic Ferrisol
TU Cong, ZHENG Chun-Rong and CHEN Huai-Man
Laboratory of Material Cycling in Pedosphere, Institute of Soil Science, the Chinese Academy of Sciences, P. O. Box 821, Nanjing 210008 (China)
ABSTRACT
      The indirect influence of heavy metal contamination of soil on nutrient availability may need to be taken into consideration when determining overall effects of heavy metals. A laboratory experiment was performed to study the effects of combined pollution of Cu, Pb, Zn and Cd on soil K status as indicated by chemical fractions, adsorption-desorption and quantity/intensity (Q/I) relationship of K in a Typic Udic Ferrisol (red soil), by employing uniform design and single factor design. Compared to the control, content of exchangeable K was decreased, but that of soluble K increased in the samples contaminated with heavy metals. Due to heavy metal pollution, potassium adsorption was reduced by 5 to 22%, whereas the desorption percentage of adsorbed K increased by 2 to 32%. The Q/I curves shifted downward, potassium buffering capacity (PBCK) decreased, and equilibrium activity ratio values (ARKo) increased with increasing heavy metal pollution. These influences followed the sequences of Pb>Cu>Zn and combined pollution>individual metals. Displacement of K from cation exchange sites and decrease in soil cation exchange capacity due to heavy metals led to changes of soil K behaviour. The findings suggest that heavy metal pollution of soil might aggravate the degradation of soil K fertility by decreasing K adsorption and buffering capacity and increasing desorption.
Key Words:  heavy metals, potassium behaviors, Typic Udic Ferrisol
Citation: Tu, C., Zheng, C. R. and Chen, H. M. 2000. Effect of heavy metal pollution on potassium behavior in Typic Udic Ferrisol. Pedosphere. 10(1): 21-30.
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