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Acid Release from an Acid Sulfate Soil Sample Under Successive Extractions with Different ExtractantsEnglish Full Text

C. LIN , M. M. ISLAM , R. T. BUSH , L. A. SULLIVAN and M. D. MELVILLE Centre for Acid Sulfate Soil Research, Southern Cross University, Lismore, NSW 2480 (Australia) School of Geography, The University of New South Wales, Sydney, NSW 2052 (Australia

Abstract: An acid sulfate soil sample was successively extracted with deionized water, 1 mol L-1 KCl and 0.000 5 mol L-l Ca(OH)2 solutions. The results showed that only very small amounts of acidity were extracted by deionized water, possibly through slow jarosite hydrolysis. Acid release through jarosite hydrolysis was greatly enhanced by Ca(OH)2 extraction at the expense of the added OH- being neutralized by the acid released. Successive extraction of the sample with KCl removed the largest amounts of acidity from the sample. However, it is likely that the major form of acidity released by KCl extraction was exchangeable acidity. The results also show the occurrence of low or non charged Al and Fe species in water and Ca(OH)2 extracts after first a few extractions. It appears that such a phenomenon was related to a decreasing EC value with increasing number of extractions.
  • Series:

    (D) Agriculture

  • Subject:

    Fundamental Science of Agriculture; Agronomy

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